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Condensed Matter > Materials Science

arXiv:2212.04404v1 (cond-mat)
[Submitted on 8 Dec 2022 ]

Title: The Effect of short-range order on the viscosity and crystallization of Al-Mg melts

Title: 短程有序对Al-Mg熔体粘度和结晶的影响

Authors:Elizaveta A. Batalova, Larisa V. Kamaeva, Nikolay M. Chtchelkatchev
Abstract: In this work, using the methods of viscosimetry and thermal analysis, the concentration changes in the values of the supercooling viscosity of Al-Mg melts with Mg content from 2.5 to 95 at.% are studied. It is shown that the temperature dependences of viscosity are well described by an exponential dependence. The concentration dependence of viscosity is not monotonous and reflects a change in the chemical short-range order in the liquid phase. The concentration dependence of supercooling of Al-Mg melts is determined by the type of solid phase formed during solidification, and also reflects the most significant changes in the chemical short-range order in the liquid phase at 20 and 80 at.% Mg. Al-Mg alloys in the concentration ranges: 0-10, 40-50 and 90-100 at.% Mg are prone to non-equilibrium crystallization, the formation of quasi-eutectics and solidification without intermediate intermetallic phases.
Abstract: 在本工作中,使用粘度测量和热分析的方法,研究了Mg含量从2.5至95 at.%的Al-Mg熔体的过冷粘度值的浓度变化。 结果表明,粘度的温度依赖性可以用指数依赖关系很好地描述。 粘度的浓度依赖性不是单调的,并反映了液相中化学短程有序的变化。 Al-Mg熔体的过冷度的浓度依赖性取决于固态相形成的方式,同时也反映了液相中化学短程有序在20和80 at.% Mg时最显著的变化。Al-Mg合金在浓度范围:0-10、40-50和90-100 at.% Mg时容易发生非平衡结晶,形成准共晶以及无中间金属间相的凝固。
Comments: 8 pages, 4 figures
Subjects: Materials Science (cond-mat.mtrl-sci) ; Chemical Physics (physics.chem-ph); Computational Physics (physics.comp-ph)
Cite as: arXiv:2212.04404 [cond-mat.mtrl-sci]
  (or arXiv:2212.04404v1 [cond-mat.mtrl-sci] for this version)
  https://doi.org/10.48550/arXiv.2212.04404
arXiv-issued DOI via DataCite

Submission history

From: Nikolay Chtchelkatchev [view email]
[v1] Thu, 8 Dec 2022 17:02:55 UTC (1,423 KB)
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