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Condensed Matter > Materials Science

arXiv:2309.01062 (cond-mat)
[Submitted on 3 Sep 2023 ]

Title: Validation of the Wiedemann-Franz Law in solid and molten tungsten above 2000 K through thermal conductivity measurements via steady state temperature differential radiometry

Title: 通过稳态温度差辐射测温法在2000 K以上的固态和熔融钨中验证维德曼-弗兰兹定律

Authors:Milena Milich, Hunter B. Schonfeld, Konstantinos Boboridis, Davide Robba, Luka Vlahovic, Rudy Konings, Jeffrey L. Braun, John T. Gaskins, Niraj Bhatt, Ashutosh Giri, Patrick E. Hopkins
Abstract: We measure the thermal conductivity of solid and molten tungsten using Steady State Temperature Differential Radiometry. We demonstrate that the thermal conductivity can be well described by application of Wiedemann-Franz Law to electrical resistivity data, thus suggesting the validity of Wiedemann-Franz Law to capture the electronic thermal conductivity of metals in their molten phase. We further support this conclusion using ab initio molecular dynamics simulations with a machine-learned potential. Our results show that at these high temperatures, the vibrational contribution to thermal conductivity is negligible compared to the electronic component.
Abstract: 我们使用稳态温度差辐射测量法测量固态和熔融钨的热导率。 我们证明,通过将维德曼-弗兰兹定律应用于电电阻率数据,可以很好地描述热导率,从而表明维德曼-弗兰兹定律在捕捉金属熔融相中的电子热导率方面是有效的。 我们进一步利用机器学习势的从头算分子动力学模拟支持这一结论。 我们的结果表明,在这些高温下,振动对热导率的贡献相对于电子成分可以忽略不计。
Subjects: Materials Science (cond-mat.mtrl-sci)
Cite as: arXiv:2309.01062 [cond-mat.mtrl-sci]
  (or arXiv:2309.01062v1 [cond-mat.mtrl-sci] for this version)
  https://doi.org/10.48550/arXiv.2309.01062
arXiv-issued DOI via DataCite

Submission history

From: Parick Hopkins [view email]
[v1] Sun, 3 Sep 2023 03:07:34 UTC (2,582 KB)
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