标题： 冰-水界面能从冰成核实验数据中斜率法的批判性分析（附评论） 显示英文标题

标题： Critical analysis of the slope method for estimation of ice-water interfacial energy from ice nucleation experimental data (with reviews)

摘要： 基于实验冰成核速率数据与归一化温度的斜率评估冰-水界面能的既定程序在本工作中被批判性分析。 在Murray等人的工作中发现冰-水界面能的估计结果不一致。 [物理化学化学物理，2010年，12卷，10380-10387页]。 不一致的来源在于用于实验冰成核数据拟合的不当回归方法，本文提出了冰-水界面能的正确估计，并讨论了斜率方法的限制。 显示英文摘要

摘要： An established procedure for the estimation of ice-water interfacial energy based on evaluation of the slope of the experimental ice nucleation rate data versus scaled temperature is critically analyzed in this work. An inconsistent estimate of the ice-water interfacial energy is found in the work of Murray et al. [Phys. Chem. Chem. Phys., 2010, 12, 10380-10387]. The source of the inconsistency is identified in an inappropriate regression method used for experimental ice nucleation data fitting, a correct estimate of the ice-water interfacial energy is presented, and limits of the slope method are discussed.